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|Section2= |Section3= |Section4= |Section8= }} Germanium dioxide, also called germanium oxide and germania, is the inorganic compound with the chemical formula GeO2. It is the main commercial source of germanium. It also forms as a passivation layer on pure germanium in contact with atmospheric oxygen. ==Structure== The two predominant polymorphs of GeO2 are hexagonal and tetragonal. Hexagonal GeO2 has the same structure as β-quartz, with germanium having coordination number 4. Tetragonal GeO2 (the mineral argutite) has the rutile-like structure seen in stishovite. In this motif, germanium has the coordination number 6. An amorphous (glassy) form of GeO2 is similar to fused silica. Germanium dioxide can be prepared in both crystalline and amorphous forms. At ambient pressure the amorphous structure is formed by a network of GeO4 tetrahedra. At elevated pressure up to approximately 9 GPa the germanium average coordination number steadily increases from 4 to around 5 with a corresponding increase in the Ge-O bond distance. At higher pressures, up to approximately 15 GPa, the germanium coordination number increases to 6 and the dense network structure is composed of GeO6 octahedra. When the pressure is subsequently reduced, the structure reverts to the tetrahedral form.〔〔 At high pressure, the rutile form converts to an orthorhombic CaCl2 form.〔Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure, J. Haines, J. M.Léger, C.Chateau, A. S.Pereira, Physics and Chemistry of Minerals, 27, 8 ,(2000), 575–582,〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Germanium dioxide」の詳細全文を読む スポンサード リンク
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